WEKO3
アイテム
{"_buckets": {"deposit": "c87c46c7-4cd2-475a-b561-65645d65a547"}, "_deposit": {"created_by": 18, "id": "6771", "owners": [18], "pid": {"revision_id": 0, "type": "depid", "value": "6771"}, "status": "published"}, "_oai": {"id": "oai:muroran-it.repo.nii.ac.jp:00006771", "sets": ["46", "300", "301"]}, "author_link": ["43637", "4707", "754", "43635", "4708", "41167"], "item_79_biblio_info_10": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2007-11-30", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1-2", "bibliographicPageEnd": "124", "bibliographicPageStart": "117", "bibliographicVolumeNumber": "77", "bibliographic_titles": [{"bibliographic_title": "Applied catalysis. B, Environmental", "bibliographic_titleLang": "en"}]}]}, "item_79_description_23": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_79_description_7": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "The catalytic activities of various noble metals (Pt, Pd, Rh, and Ru) supported on siliceous SBA-15 and Al-containing SBA-15 (AlSBA-15) for hydrodesulfurization (HDS) of thiophene at 350 C were investigated. AlSBA-15 was prepared by a grafting method using aluminum isopropoxide (Al(OC3H7)3) hexane solution. The HDS activity of Pt/AlSBA-15 catalyst was the highest among those of various supported noble metal catalysts, and this activity was higher than that of commercial CoMo/Al2O3 HDS catalyst. The catalysts were characterized by XRD analysis, hydrogen adsorption, 2-propanol dehydration, cumene cracking, and FT-IR. Dispersion of Pt on SBA-15 was remarkably enhanced by Al grafting. It was revealed that the acidity of AlSBA-15 was higher than that of SBA-15. Furthermore, Brønsted acid sites were observed on AlSBA-15. FT-IR spectra of thiophene adsorbed on AlSBA-15 indicate that thiophene molecules interact with Brønsted acid sites on the surface of AlSBA-15 and that the strength of this interaction was stronger than that of SBA-15. Based on these results, thiophene molecules activated on Brønsted acid site of AlSBA-15 and hydrogen molecules activate to form spillover hydrogen on Pt particles in Pt/AlSBA-15 catalyst in the HDS of thiophene.", "subitem_description_language": "en", "subitem_description_type": "Abstract"}]}, "item_79_link_17": {"attribute_name": "出版者版へのリンク", "attribute_value_mlt": [{"subitem_link_text": "10.1016/j.apcatb.2007.07.012", "subitem_link_url": "https://doi.org/10.1016/j.apcatb.2007.07.012"}]}, "item_79_link_5": {"attribute_name": "室蘭工業大学研究者データベースへのリンク", "attribute_value_mlt": [{"subitem_link_text": "神田 康晴(KANDA Yasuharu)", "subitem_link_url": "http://rdsoran.muroran-it.ac.jp/html/100000202_ja.html"}, {"subitem_link_text": "上道 芳夫(UEMICHI Yoshio)", "subitem_link_url": "http://rdsoran.muroran-it.ac.jp/html/100000169_ja.html"}]}, "item_79_publisher_11": {"attribute_name": "出版者", "attribute_value_mlt": [{"subitem_publisher": "Elsevier B.V.", "subitem_publisher_language": "en"}]}, "item_79_relation_15": {"attribute_name": "論文ID(NAID)", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "120000802143", "subitem_relation_type_select": "NAID"}}]}, "item_79_relation_18": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "10.1016/j.apcatb.2007.07.012", "subitem_relation_type_select": "DOI"}}]}, "item_79_relation_20": {"attribute_name": "参考URL", "attribute_value_mlt": [{"subitem_relation_type_id": {"subitem_relation_type_id_text": "https://www.elsevier.com/locate/issn/09263373", "subitem_relation_type_select": "URI"}}]}, "item_79_source_id_12": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "09263373", "subitem_source_identifier_type": "PISSN"}]}, "item_79_source_id_14": {"attribute_name": "書誌レコードID", "attribute_value_mlt": [{"subitem_source_identifier": "AA1082551X", "subitem_source_identifier_type": "NCID"}, {"subitem_source_identifier": "AA11523662", "subitem_source_identifier_type": "NCID"}]}, "item_79_subject_9": {"attribute_name": "日本十進分類法", "attribute_value_mlt": [{"subitem_subject": "575.52", "subitem_subject_scheme": "NDC"}]}, "item_79_text_4": {"attribute_name": "著者ID(非表示)", "attribute_value_mlt": [{"subitem_text_value": "1000070447085"}]}, "item_79_version_type_21": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_access_right": {"attribute_name": "アクセス権", "attribute_value_mlt": [{"subitem_access_right": "open access", "subitem_access_right_uri": "http://purl.org/coar/access_right/c_abf2"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorAffiliations": [{"affiliationNameIdentifiers": [{"affiliationNameIdentifier": "10103", "affiliationNameIdentifierScheme": "kakenhi"}], "affiliationNames": [{"affiliationName": "室蘭工業大学", "affiliationNameLang": "ja"}, {"affiliationName": "Muroran Institute of Technology", "affiliationNameLang": "en"}]}], "creatorNames": [{"creatorName": "KANDA, Yasuharu", "creatorNameLang": "en"}, {"creatorName": "カンダ, ヤスハル", "creatorNameLang": "ja-Kana"}, {"creatorName": "神田, 康晴", "creatorNameLang": "ja"}], "familyNames": [{"familyName": "KANDA", "familyNameLang": "en"}, {"familyName": "カンダ", "familyNameLang": "ja-Kana"}, {"familyName": "神田", "familyNameLang": "ja"}], "givenNames": [{"givenName": " Yasuharu", "givenNameLang": "en"}, {"givenName": "ヤスハル", "givenNameLang": "ja-Kana"}, {"givenName": "康晴", "givenNameLang": "ja"}], "nameIdentifiers": [{"nameIdentifier": "4707", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000070447085", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000070447085"}]}, {"creatorAffiliations": [{"affiliationNameIdentifiers": [], "affiliationNames": [{"affiliationName": "", "affiliationNameLang": "ja"}]}], "creatorNames": [{"creatorName": "AIZAWA, Tomohiro", "creatorNameLang": "en"}], "familyNames": [{"familyName": "AIZAWA", "familyNameLang": "en"}], "givenNames": [{"givenName": "Tomohiro", "givenNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "43635", "nameIdentifierScheme": "WEKO"}]}, {"creatorAffiliations": [{"affiliationNameIdentifiers": [], "affiliationNames": [{"affiliationName": "", "affiliationNameLang": "ja"}]}], "creatorNames": [{"creatorName": "小林, 隆夫", "creatorNameLang": "ja"}, {"creatorName": "KOBAYASHI, Takao", "creatorNameLang": "en"}, {"creatorName": "コバヤシ, タカオ", "creatorNameLang": "ja-Kana"}], "familyNames": [{"familyName": "小林", "familyNameLang": "ja"}, {"familyName": "KOBAYASHI", "familyNameLang": "en"}, {"familyName": "コバヤシ", "familyNameLang": "ja-Kana"}], "givenNames": [{"givenName": "隆夫", "givenNameLang": "ja"}, {"givenName": "Takao", "givenNameLang": "en"}, {"givenName": "タカオ", "givenNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "41167", "nameIdentifierScheme": "WEKO"}]}, {"creatorAffiliations": [{"affiliationNameIdentifiers": [], "affiliationNames": [{"affiliationName": "", "affiliationNameLang": "ja"}]}], "creatorNames": [{"creatorName": "UEMICHI, Yoshio", "creatorNameLang": "en"}, {"creatorName": "上道, 芳夫", "creatorNameLang": "ja"}, {"creatorName": "ウエミチ, ヨシオ", "creatorNameLang": "ja-Kana"}], "familyNames": [{"familyName": "UEMICHI", "familyNameLang": "en"}, {"familyName": "上道", "familyNameLang": "ja"}, {"familyName": "ウエミチ", "familyNameLang": "ja-Kana"}], "givenNames": [{"givenName": " Yoshio", "givenNameLang": "en"}, {"givenName": "芳夫", "givenNameLang": "ja"}, {"givenName": "ヨシオ", "givenNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "4708", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000090168659", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000090168659"}]}, {"creatorNames": [{"creatorName": "NAMBA, Seitaro", "creatorNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "43637", "nameIdentifierScheme": "WEKO"}]}, {"creatorAffiliations": [{"affiliationNameIdentifiers": [], "affiliationNames": [{"affiliationName": "", "affiliationNameLang": "ja"}]}], "creatorNames": [{"creatorName": "杉岡, 正敏", "creatorNameLang": "ja"}, {"creatorName": "スギオカ, マサトシ", "creatorNameLang": "ja-Kana"}, {"creatorName": "SUGIOKA, Masatoshi", "creatorNameLang": "en"}], "familyNames": [{"familyName": "杉岡", "familyNameLang": "ja"}, {"familyName": "スギオカ", "familyNameLang": "ja-Kana"}, {"familyName": "SUGIOKA", "familyNameLang": "en"}], "givenNames": [{"givenName": " 正敏", "givenNameLang": "ja"}, {"givenName": "マサトシ", "givenNameLang": "ja-Kana"}, {"givenName": "Masatoshi", "givenNameLang": "en"}], "nameIdentifiers": [{"nameIdentifier": "754", "nameIdentifierScheme": "WEKO"}, {"nameIdentifier": "1000080001329", "nameIdentifierScheme": "NRID", "nameIdentifierURI": "https://nrid.nii.ac.jp/ja/nrid/1000080001329"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2016-02-15"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "ACB77(1-2)p117.pdf", "filesize": [{"value": "463.3 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_note", "mimetype": "application/pdf", "size": 463300.0, "url": {"label": "ACB77(1-2)p117.pdf", "objectType": "fulltext", "url": "https://muroran-it.repo.nii.ac.jp/record/6771/files/ACB77(1-2)p117.pdf"}, "version_id": "c2ce258b-a845-4bc1-b11d-278736b9b3b3"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "acid rain prevention", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "hydrodesulfurization", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "thiophene", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "SBA-15", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}, {"subitem_subject": "noble metal catalyst", "subitem_subject_language": "en", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "Preparation of highly active AlSBA-15-supported platinum catalyst for thiophene hydrodesulfurization", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "Preparation of highly active AlSBA-15-supported platinum catalyst for thiophene hydrodesulfurization", "subitem_title_language": "en"}]}, "item_type_id": "79", "owner": "18", "path": ["46", "300", "301"], "permalink_uri": "http://hdl.handle.net/10258/347", "pubdate": {"attribute_name": "PubDate", "attribute_value": "2008-01-08"}, "publish_date": "2008-01-08", "publish_status": "0", "recid": "6771", "relation": {}, "relation_version_is_last": true, "title": ["Preparation of highly active AlSBA-15-supported platinum catalyst for thiophene hydrodesulfurization"], "weko_shared_id": -1}
Preparation of highly active AlSBA-15-supported platinum catalyst for thiophene hydrodesulfurization
http://hdl.handle.net/10258/347
http://hdl.handle.net/10258/347db6b40b0-a6d9-48c9-8433-99aae9025fea
名前 / ファイル | ライセンス | アクション |
---|---|---|
ACB77(1-2)p117.pdf (463.3 kB)
|
|
Item type | 学術雑誌論文 / Journal Article.(1) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
公開日 | 2008-01-08 | |||||||||||
タイトル | ||||||||||||
言語 | en | |||||||||||
タイトル | Preparation of highly active AlSBA-15-supported platinum catalyst for thiophene hydrodesulfurization | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | acid rain prevention | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | hydrodesulfurization | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | thiophene | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | SBA-15 | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | noble metal catalyst | |||||||||||
資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | journal article | |||||||||||
アクセス権 | ||||||||||||
アクセス権 | open access | |||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
著者 |
神田, 康晴
× 神田, 康晴
WEKO
4707
× AIZAWA, Tomohiro× 小林, 隆夫× 上道, 芳夫× NAMBA, Seitaro× 杉岡, 正敏 |
|||||||||||
室蘭工業大学研究者データベースへのリンク | ||||||||||||
神田 康晴(KANDA Yasuharu) | ||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000202_ja.html | ||||||||||||
室蘭工業大学研究者データベースへのリンク | ||||||||||||
上道 芳夫(UEMICHI Yoshio) | ||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000169_ja.html | ||||||||||||
抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | The catalytic activities of various noble metals (Pt, Pd, Rh, and Ru) supported on siliceous SBA-15 and Al-containing SBA-15 (AlSBA-15) for hydrodesulfurization (HDS) of thiophene at 350 C were investigated. AlSBA-15 was prepared by a grafting method using aluminum isopropoxide (Al(OC3H7)3) hexane solution. The HDS activity of Pt/AlSBA-15 catalyst was the highest among those of various supported noble metal catalysts, and this activity was higher than that of commercial CoMo/Al2O3 HDS catalyst. The catalysts were characterized by XRD analysis, hydrogen adsorption, 2-propanol dehydration, cumene cracking, and FT-IR. Dispersion of Pt on SBA-15 was remarkably enhanced by Al grafting. It was revealed that the acidity of AlSBA-15 was higher than that of SBA-15. Furthermore, Brønsted acid sites were observed on AlSBA-15. FT-IR spectra of thiophene adsorbed on AlSBA-15 indicate that thiophene molecules interact with Brønsted acid sites on the surface of AlSBA-15 and that the strength of this interaction was stronger than that of SBA-15. Based on these results, thiophene molecules activated on Brønsted acid site of AlSBA-15 and hydrogen molecules activate to form spillover hydrogen on Pt particles in Pt/AlSBA-15 catalyst in the HDS of thiophene. | |||||||||||
言語 | en | |||||||||||
書誌情報 |
en : Applied catalysis. B, Environmental 巻 77, 号 1-2, p. 117-124, 発行日 2007-11-30 |
|||||||||||
出版者 | ||||||||||||
言語 | en | |||||||||||
出版者 | Elsevier B.V. | |||||||||||
出版者版へのリンク | ||||||||||||
10.1016/j.apcatb.2007.07.012 | ||||||||||||
https://doi.org/10.1016/j.apcatb.2007.07.012 | ||||||||||||
DOI | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | 10.1016/j.apcatb.2007.07.012 | |||||||||||
論文ID(NAID) | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
識別子タイプ | NAID | |||||||||||
関連識別子 | 120000802143 | |||||||||||
日本十進分類法 | ||||||||||||
主題Scheme | NDC | |||||||||||
主題 | 575.52 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | PISSN | |||||||||||
収録物識別子 | 09263373 | |||||||||||
書誌レコードID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA1082551X | |||||||||||
書誌レコードID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA11523662 | |||||||||||
参考URL | ||||||||||||
識別子タイプ | URI | |||||||||||
関連識別子 | https://www.elsevier.com/locate/issn/09263373 | |||||||||||
著者版フラグ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
フォーマット | ||||||||||||
内容記述タイプ | Other | |||||||||||
内容記述 | application/pdf |