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1.2x10-5 Pa の酸素、エチレンに接触しているCsおよびRe 添加Ag 触媒表面のin situ XPS 分析
http://hdl.handle.net/10258/1007
http://hdl.handle.net/10258/100721ce988f-a861-4bf8-bac9-012855bdd55a
名前 / ファイル | ライセンス | アクション |
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kiyo61_pp63-73.pdf (3.9 MB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-04-12 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | 1.2x10-5 Pa の酸素、エチレンに接触しているCsおよびRe 添加Ag 触媒表面のin situ XPS 分析 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | In situ XPS Analysis of Cs and Re-doped Silver Catalyst Surfaces Exposed to Oxygen and Ethylene at 1.2x10-5 Pa | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | XPS | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | in situ measurement | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Cesium | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Rhenium | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Silver catalyst | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Oxydation state | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Surface oxygen species | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
宮本, 政明
× 宮本, 政明× 千田, 卓也× 荒山, 岳人× 菖蒲, 明己 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Dynamic behaviors of electronic charges and surface concentrations of Cs, Re, and O on self-supporting disc surfaces of Cs and Re-doped Ag powder catalyst during the operation of O2- and C2H4-jet were measured at 1.2x10-5 Pa and 483 K using a conventional XPS. Exposure of the disc surface to O2-jet caused slight oxidations of Cs and Re, mild migrations of Cs and Re into bulk phase,and an increase of surface oxygen concentration with exposure time, while the exposure to C2H4-jet resulted in a slight reduction of Cs and a decrease of surface oxygen concentration. Deconvolution of O1s spectra resulted in five core spectra, of which the composition ratio changed drastically with exposure time Furthermore, relationships between the parameters mentioned above and pressure ofactive gases in contact with the disc surface were discussed. | |||||
言語 | en | |||||
書誌情報 |
ja : 室蘭工業大学紀要 en : Memoirs of the Muroran Institute of Technology 巻 61, p. 63-73, 発行日 2012-03-27 |
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注記 | ||||||
内容記述タイプ | Other | |||||
内容記述 | 学術論文 | |||||
言語 | ja | |||||
出版者 | ||||||
言語 | ja | |||||
出版者 | 室蘭工業大学 | |||||
論文ID(NAID) | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | NAID | |||||
関連識別子 | 120003989366 | |||||
日本十進分類法 | ||||||
主題Scheme | NDC | |||||
主題 | 433 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 13442708 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11912609 | |||||
権利 | ||||||
言語 | ja | |||||
権利情報 | 室蘭工業大学 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |