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Magnetic susceptibility of vanadium garnets NaPb2Co2V3O12 and NaPb2Ni2V3O12
http://hdl.handle.net/10258/416
http://hdl.handle.net/10258/4169a1d52db-e3cf-4201-9ace-46ebe72db373
名前 / ファイル | ライセンス | アクション |
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jpcs66(1)p177.pdf (637.6 kB)
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Item type | 学術雑誌論文 / Journal Article.(1) | |||||||||||
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公開日 | 2008-10-02 | |||||||||||
タイトル | ||||||||||||
言語 | en | |||||||||||
タイトル | Magnetic susceptibility of vanadium garnets NaPb2Co2V3O12 and NaPb2Ni2V3O12 | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | A. Inorganic compounds | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | A. Oxides | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | B. Chemical synthesis | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | D. Magnetic properties | |||||||||||
資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | journal article | |||||||||||
アクセス権 | ||||||||||||
アクセス権 | open access | |||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
著者 |
永田, 正一
× 永田, 正一× YAMAGISHI, Takumi× AWAKA, Kenji× 阿波加, 淳司× 戎, 修二
WEKO
197
× 近澤, 進 |
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室蘭工業大学研究者データベースへのリンク | ||||||||||||
戎 修二(EBISU Shuji) | ||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000219_ja.html | ||||||||||||
室蘭工業大学研究者データベースへのリンク | ||||||||||||
近澤 進(CHIKAZAWA Susumu) | ||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000196_ja.html | ||||||||||||
抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | Vanadium garnets NaPb2Co2V3O12 and NaPb2Ni2V3O12 have been successfully synthesized. The X-ray diffraction experiments indicate that these compounds have the garnet structure of cubic symmetry of space group Ia3?d(Oh10) with the lattice constant of 12.742 Å (NaPb2Co2V3O12) and 12.666 Å (NaPb2Ni2V3O12), respectively. The magnetic susceptibility of NaPb2Ni2V3O12 shows the Curie Weiss paramagnetic behavior between 4.2 and 350 K. The effective magnetic moment μeff of NaPb2Ni2V3O12 is 3.14 μB due to Ni2+ ion at A-site and the Weiss constant is -3.67 K (antiferromagnetic sign). For NaPb2Co2V3O12, the simple Curie Weiss law cannot be applicable. The ground state is the spin doublet E2(t26e) and the first excited state is spin quartet T4(t25e), according to Tanabe-Sugano energy diagram on the basis of octahedral crystalline symmetry. This excited spin quartet state just a bit higher than ground state influences strongly the complex temperature dependence of magnetic susceptibility for NaPb2Co2V3O12. | |||||||||||
言語 | en | |||||||||||
書誌情報 |
en : Journal of physics and chemistry of solids 巻 66, 号 1, p. 177-183, 発行日 2005-01 |
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出版者 | ||||||||||||
言語 | en | |||||||||||
出版者 | Elsevier | |||||||||||
出版者版へのリンク | ||||||||||||
10.1016/j.jpcs.2004.08.046 | ||||||||||||
https://doi.org/10.1016/j.jpcs.2004.08.046 | ||||||||||||
DOI | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | 10.1016/j.jpcs.2004.08.046 | |||||||||||
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関連タイプ | isVersionOf | |||||||||||
識別子タイプ | NAID | |||||||||||
関連識別子 | 120000802294 | |||||||||||
日本十進分類法 | ||||||||||||
主題Scheme | NDC | |||||||||||
主題 | 428 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | PISSN | |||||||||||
収録物識別子 | 00223697 | |||||||||||
書誌レコードID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA00704949 | |||||||||||
書誌レコードID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA11534013 | |||||||||||
参考URL | ||||||||||||
識別子タイプ | URI | |||||||||||
関連識別子 | https://www.elsevier.com/locate/issn/00223697 | |||||||||||
著者版フラグ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
フォーマット | ||||||||||||
内容記述タイプ | Other | |||||||||||
内容記述 | application/pdf |