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Synthesis and crystallographic studies of garnet-type AgCa2Mn2V3O12 and NaPb2Mn2V3O12
http://hdl.handle.net/10258/415
http://hdl.handle.net/10258/4157d27f6b6-369c-4bf3-b6ba-3f600ed6cad4
名前 / ファイル | ライセンス | アクション |
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JPCS69(7)_1740-1746.pdf (552.8 kB)
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Item type | 学術雑誌論文 / Journal Article.(1) | |||||
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公開日 | 2008-09-01 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Synthesis and crystallographic studies of garnet-type AgCa2Mn2V3O12 and NaPb2Mn2V3O12 | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Inorganic compounds | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Oxides | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Chemical synthesis | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | X-ray diffraction | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | Crystal structure | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
阿波加, 淳司
× 阿波加, 淳司× KIJIMA, Norihito× AKIMOTO, Junji× 永田, 正一 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | High-purity powder specimens of AgCa2Mn2V3O12 and NaPb2Mn2V3O12 have been successfully synthesized by solid-state chemical reaction. The Rietveld refinements from X-ray powder diffraction data verified that these compounds have the garnet-type structure (space group Ia-3d, No. 230) with the lattice constant of a = 12.596(2) Å for AgCa2Mn2V3O12 and a = 12.876(2) Å for NaPb2Mn2V3O12. Calculation of the bond valence sum supported that Mn is divalent and V is pentavalent in these garnets. Estimation of the quadratic elongation and the bond angle variance showed that the distortions of the MnO6 octahedra and the VO4 tetrahedra are significantly suppressed. Our new results of AgCa2Mn2V3O12 and NaPb2Mn2V3O12 are compared to those of AgCa2M2V3O12 and NaPb2M2V3O12 (M = Mg, Co, Ni, Zn). | |||||
言語 | en | |||||
書誌情報 |
en : Journal of physics and chemistry of solids 巻 69, 号 7, p. 1740-1746, 発行日 2008-07 |
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出版者 | ||||||
言語 | en | |||||
出版者 | Elsevier | |||||
出版者版へのリンク | ||||||
10.1016/j.jpcs.2007.12.021 | ||||||
https://doi.org/10.1016/j.jpcs.2007.12.021 | ||||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1016/j.jpcs.2007.12.021 | |||||
論文ID(NAID) | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | NAID | |||||
関連識別子 | 120001671528 | |||||
日本十進分類法 | ||||||
主題Scheme | NDC | |||||
主題 | 428 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 00223697 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00704949 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA11534013 | |||||
参考URL | ||||||
識別子タイプ | URI | |||||
関連識別子 | https://www.elsevier.com/locate/issn/00223697 | |||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |