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Preparation and performance of noble metal phosphides supported on silica as new hydrodesulfurization catalysts
http://hdl.handle.net/10258/813
http://hdl.handle.net/10258/8130a1e8b2f-05d7-4910-98cd-93a6616cd653
名前 / ファイル | ライセンス | アクション |
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Appl.Catal.A386_171_2010.pdf (1.1 MB)
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Item type | 学術雑誌論文 / Journal Article.(1) | |||||||||||
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公開日 | 2012-03-05 | |||||||||||
タイトル | ||||||||||||
言語 | en | |||||||||||
タイトル | Preparation and performance of noble metal phosphides supported on silica as new hydrodesulfurization catalysts | |||||||||||
言語 | ||||||||||||
言語 | eng | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | Hydrodesulfurization | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | Thiophene | |||||||||||
キーワード | ||||||||||||
言語 | en | |||||||||||
主題Scheme | Other | |||||||||||
主題 | Noble metal phosphide catalyst | |||||||||||
資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | journal article | |||||||||||
アクセス権 | ||||||||||||
アクセス権 | open access | |||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
著者 |
神田, 康晴
× 神田, 康晴
WEKO
4707
× 天満, 千智× NAKATA, Keisuke× 小林, 隆夫× 杉岡, 正敏× 上道, 芳夫 |
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室蘭工業大学研究者データベースへのリンク | ||||||||||||
神田 康晴(KANDA Yasuharu) | ||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000202_ja.html | ||||||||||||
室蘭工業大学研究者データベースへのリンク | ||||||||||||
上道 芳夫(UEMICHI Yoshio) | ||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000169_ja.html | ||||||||||||
抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | Preparation of noble metal (NM) (Rh, Pd, Ru, Pt) phosphide species and their catalytic activities for hydrodesulfurization (HDS) of thiophene were investigated. Noble metal phosphides (NMXPY) catalysts were prepared by reduction of P-added NM (NM-P) supported on silica (SiO_2) with hydrogen. Hydrogen consumption peaks at around 350–700 °C, which were attributed to the formation of NMXPY, were observed in temperature-programmed reduction (TPR) spectra of all NM-P/SiO_2. Furthermore, X-ray diffraction (XRD) patterns of NM-P/SiO_2 indicate that NMXPY (Rh_2P, Pd_<4.8>P, Ru_2P, PtP_2) were formed by hydrogen reduction at high temperature. The reduction temperature strongly affected HDS activities of NM-P/SiO_2 catalysts. The NM-P/SiO_2 catalysts, other than Pt, showed higher HDS activities than NM/SiO_2 catalysts. The HDS activity of the Rh-P/SiO_2 catalyst was the highest among those of NM-P/SiO2 catalysts. This activity was higher than that of the Ni-P catalyst and was the same as that of pre-sulfided CoMoP/Al_2O_3 catalyst. Furthermore, the Rh-P/SiO_2 catalyst showed stable activity even after reaction for 30 h. The XRD, transmission electron microscopy (TEM), and energy dispersive X-ray spectroscopy (EDS) results revealed that the formation of small Rh_2P particles and suitable P addition to form Rh_2P caused the high HDS activity of the Rh-P catalyst. | |||||||||||
言語 | en | |||||||||||
書誌情報 |
en : Applied catalysis. A, General 巻 386, 号 1-2, p. 171-178, 発行日 2010-09-30 |
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出版者 | ||||||||||||
言語 | en | |||||||||||
出版者 | Elsevier B.V. | |||||||||||
出版者版へのリンク | ||||||||||||
10.1016/j.apcata.2010.07.045 | ||||||||||||
https://doi.org/10.1016/j.apcata.2010.07.045 | ||||||||||||
DOI | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
識別子タイプ | DOI | |||||||||||
関連識別子 | 10.1016/j.apcata.2010.07.045 | |||||||||||
論文ID(NAID) | ||||||||||||
関連タイプ | isVersionOf | |||||||||||
識別子タイプ | NAID | |||||||||||
関連識別子 | 120003895512 | |||||||||||
日本十進分類法 | ||||||||||||
主題Scheme | NDC | |||||||||||
主題 | 570 | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | PISSN | |||||||||||
収録物識別子 | 0926860X | |||||||||||
書誌レコードID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA10821202 | |||||||||||
書誌レコードID | ||||||||||||
収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AA1152363X | |||||||||||
参考URL | ||||||||||||
識別子タイプ | URI | |||||||||||
関連識別子 | https://www.sciencedirect.com/science/journal/0926860X | |||||||||||
著者版フラグ | ||||||||||||
出版タイプ | AM | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||
フォーマット | ||||||||||||
内容記述タイプ | Other | |||||||||||
内容記述 | application/pdf |