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Cis and trans radicals generated in helical poly(propargyl acetate)s prepared using a [Rh(norbornadiene)Cl]2 catalyst
http://hdl.handle.net/10258/661
http://hdl.handle.net/10258/66198533ec7-8fe4-40f2-b68e-29ec533e1c9b
名前 / ファイル | ライセンス | アクション |
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Polymer_52(3)p646-651.pdf (951.2 kB)
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Item type | 学術雑誌論文 / Journal Article.(1) | |||||||||||||||||
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公開日 | 2011-09-14 | |||||||||||||||||
タイトル | ||||||||||||||||||
言語 | en | |||||||||||||||||
タイトル | Cis and trans radicals generated in helical poly(propargyl acetate)s prepared using a [Rh(norbornadiene)Cl]2 catalyst | |||||||||||||||||
言語 | ||||||||||||||||||
言語 | eng | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | Poly(propargyl acetate) | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | Rh catalyst | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | Electron spin resonance | |||||||||||||||||
資源タイプ | ||||||||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
資源タイプ | journal article | |||||||||||||||||
アクセス権 | ||||||||||||||||||
アクセス権 | open access | |||||||||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||||||
著者 |
YOSHIDA, Yoshiaki
× YOSHIDA, Yoshiaki× 馬渡, 康輝
WEKO
56124
× 関, 千草
WEKO
43177
× HIRAOKI, Toshifumi× 松山, 春男× 田畑, 昌祥 |
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室蘭工業大学研究者データベースへのリンク | ||||||||||||||||||
馬渡 康輝(MAWATARI Yasuteru) | ||||||||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000132_ja.html | ||||||||||||||||||
室蘭工業大学研究者データベースへのリンク | ||||||||||||||||||
関 千草(SEKI Chigusa) | ||||||||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000264_ja.html | ||||||||||||||||||
抄録 | ||||||||||||||||||
内容記述タイプ | Abstract | |||||||||||||||||
内容記述 | The poly(propargyl acetate) (A) having a helical cis–transoid structure was stereospecifically prepared using the Rh complex catalyst, [Rh(norbornadiene)Cl]2, in MeOH or NEt3 solvent at 0 and 40 °C in moderate yield. Electron spin resonance (ESR) analysis of the polymer revealed the formation of the cis (B) and trans (C) radicals which were produced through the thermal rotational scission of the helical cis CC bonds in the main-chain during the polymerization. The spatial and geometrical structure was successfully deduced using the two analogues’ polymers in which either methyl or methylene group is deuterated, by the aide of computer simulation of the observed ESR spectra together with the calculation of spin density of the two radicals. | |||||||||||||||||
言語 | en | |||||||||||||||||
書誌情報 |
en : Polymer 巻 52, 号 3, p. 646-651, 発行日 2011-02-03 |
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出版者 | ||||||||||||||||||
言語 | en | |||||||||||||||||
出版者 | Elsevier Ltd. | |||||||||||||||||
出版者版へのリンク | ||||||||||||||||||
10.1016/j.polymer.2010.12.023 | ||||||||||||||||||
https://doi.org/10.1016/j.polymer.2010.12.023 | ||||||||||||||||||
DOI | ||||||||||||||||||
関連タイプ | isVersionOf | |||||||||||||||||
識別子タイプ | DOI | |||||||||||||||||
関連識別子 | 10.1016/j.polymer.2010.12.023 | |||||||||||||||||
論文ID(NAID) | ||||||||||||||||||
関連タイプ | isVersionOf | |||||||||||||||||
識別子タイプ | NAID | |||||||||||||||||
関連識別子 | 120003339542 | |||||||||||||||||
日本十進分類法 | ||||||||||||||||||
主題Scheme | NDC | |||||||||||||||||
主題 | 431.19 | |||||||||||||||||
ISSN | ||||||||||||||||||
収録物識別子タイプ | PISSN | |||||||||||||||||
収録物識別子 | 00323861 | |||||||||||||||||
ISSN | ||||||||||||||||||
収録物識別子タイプ | PISSN | |||||||||||||||||
収録物識別子 | 00323861 | |||||||||||||||||
書誌レコードID | ||||||||||||||||||
収録物識別子タイプ | NCID | |||||||||||||||||
収録物識別子 | AA00776983 | |||||||||||||||||
書誌レコードID | ||||||||||||||||||
収録物識別子タイプ | NCID | |||||||||||||||||
収録物識別子 | AA11537383 | |||||||||||||||||
権利 | ||||||||||||||||||
言語 | en | |||||||||||||||||
権利情報 | © 2011 Elsevier Ltd. | |||||||||||||||||
参考URL | ||||||||||||||||||
識別子タイプ | URI | |||||||||||||||||
関連識別子 | https://www.sciencedirect.com/science/journal/00323861 | |||||||||||||||||
著者版フラグ | ||||||||||||||||||
出版タイプ | AM | |||||||||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||||||
フォーマット | ||||||||||||||||||
内容記述タイプ | Other | |||||||||||||||||
内容記述 | application/pdf |