{"created":"2023-06-19T10:30:15.367566+00:00","id":10514,"links":{},"metadata":{"_buckets":{"deposit":"be795afd-63cf-4c62-a576-808c4ea4a571"},"_deposit":{"created_by":18,"id":"10514","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"10514"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00010514","sets":["216:300","46"]},"author_link":["4707","4708","58653"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2020","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"148","bibliographicPageStart":"141","bibliographicVolumeNumber":"63","bibliographic_titles":[{"bibliographic_title":"JOURNAL OF THE JAPAN PETROLEUM INSTITUTE","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Sulfur tolerance properties of rhodium phosphide (Rh2P) were qualitatively and quantitatively evaluated by the temperature-programmed sulfidation (TPS) technique. The TPS profile of the Rh/SiO2 catalyst demonstrated a peak attributed to Rh2S3 formation around 400 degrees C. The TPS profiles of P-added Rh (Rh-P) catalysts showed this peak shifted to higher temperatures and lower intensity with higher P/Rh ratio or reduction temperature. Quantitative analysis of TPS profiles revealed that the amount of reacted H2S was remarkably lower (about 80 %) with P/Rh ratio more than 1.5, compared with Rh catalyst. The amount of reacted H2S decreased with greater intensity of the Rh2P peak in the XRD pattern, indicating that Rh2P has high sulfur tolerance. Furthermore, the relationship between P/Rh ratio and S/Rh ratio (calculated from TPS profile) of Rh-P catalysts agreed with the reported S/Rh value, showing the TPS method has high validity for qualitative analysis. We conclude that the TPS technique is a superior method for evaluation of sulfur tolerance for phosphide catalysts, and Rh2P has remarkably high sulfur tolerance compared with Rh catalyst.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_text":"10.1627/jpi.63.141","subitem_link_url":"https://doi.org/10.1627/jpi.63.141"}]},"item_79_link_5":{"attribute_name":"室蘭工業大学研究者データベースへのリンク","attribute_value_mlt":[{"subitem_link_text":"神田 康晴（KANDA Yasuharu）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000202_ja.html"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"JAPAN PETROLEUM INST","subitem_publisher_language":"en"}]},"item_79_relation_18":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1627/jpi.63.141","subitem_relation_type_select":"DOI"}}]},"item_79_rights_19":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"https://creativecommons.org/licenses/by/4.0/","subitem_rights_language":"en"}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"1346-8804","subitem_source_identifier_type":"PISSN"}]},"item_79_subject_9":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Ueno, Ren","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"UEMICHI,  Yoshio","creatorNameLang":"en"},{"creatorName":"上道, 芳夫","creatorNameLang":"ja"},{"creatorName":"ウエミチ, ヨシオ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{}],"affiliationNames":[{},{}]}],"creatorNames":[{"creatorName":"KANDA,  Yasuharu","creatorNameLang":"en"},{"creatorName":"カンダ, ヤスハル","creatorNameLang":"ja-Kana"},{"creatorName":"神田, 康晴","creatorNameLang":"ja"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2022-03-23"}],"displaytype":"detail","filename":"JJPI_63_3_141.pdf","filesize":[{"value":"570.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JJPI_63_3_141","objectType":"fulltext","url":"https://muroran-it.repo.nii.ac.jp/record/10514/files/JJPI_63_3_141.pdf"},"version_id":"d01fff09-5f19-4201-ba33-bd6687da9080"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Temperature-programmed sulfidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Sulfur tolerance","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Rhodium phosphide","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydrogen sulfide","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Sulfur Tolerance Properties of Rhodium Phosphide Evaluated by a New Temperature-programmed Sulfidation Technique","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Sulfur Tolerance Properties of Rhodium Phosphide Evaluated by a New Temperature-programmed Sulfidation Technique","subitem_title_language":"en"}]},"item_type_id":"79","owner":"18","path":["46","300"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2022-03-23"},"publish_date":"2022-03-23","publish_status":"0","recid":"10514","relation_version_is_last":true,"title":["Sulfur Tolerance Properties of Rhodium Phosphide Evaluated by a New Temperature-programmed Sulfidation Technique"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-11-06T06:42:18.640010+00:00"}