@article{oai:muroran-it.repo.nii.ac.jp:00010522, author = {Sawada, Michika and Sridhar, Kandi and KANDA, Yasuharu and 神田, 康晴 and 山中, 真也 and YAMANAKA, Shinya}, issue = {1}, journal = {SCIENTIFIC REPORTS}, month = {}, note = {application/pdf, We report a synthesis strategy for pure hydroxyapatite (HAp) using an amorphous calcium carbonate (ACC) colloid as the starting source. Room-temperature phosphorylation and subsequent calcination produce pure HAp via intermediate amorphous calcium phosphate (ACP). The pre-calcined sample undergoes a competitive transformation from ACC to ACP and crystalline calcium carbonate. The water content, ACC concentration, Ca/P molar ratio, and pH during the phosphorylation reaction play crucial roles in the final phase of the crystalline phosphate compound. Pure HAp is formed after ACP is transformed from ACC at a low concentration (1 wt%) of ACC colloid (1.71 < Ca/P < 1.88), whereas Ca/P = 1.51 leads to pure beta-tricalcium phosphate. The ACP phases are precursors for calcium phosphate compounds and may determine the final crystalline phase.}, title = {Pure hydroxyapatite synthesis originating from amorphous calcium carbonate}, volume = {11}, year = {2021}, yomi = {カンダ, ヤスハル and ヤマナカ, シンヤ} }