| アイテムタイプ |
学術雑誌論文 / Journal Article.(1) |
| 公開日 |
2023-09-28 |
| 書誌情報 |
en : RSC Advances
巻 13,
号 6,
p. 3494-3504,
ページ数 11,
発行日 2023
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| タイトル |
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タイトル |
Synthesis of polynorbornadienes by ring-opening metathesis polymerization and their saturated derivatives bearing various ester groups and carboxyl groups |
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言語 |
en |
| 言語 |
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|
言語 |
eng |
| 資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
journal article |
| アクセス権 |
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アクセス権 |
open access |
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アクセス権URI |
http://purl.org/coar/access_right/c_abf2 |
| 著者 |
Lin, Xiaoxue
Shi, Jianjun
庭山, 聡美
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| 抄録 |
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内容記述タイプ |
Abstract |
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内容記述 |
Various symmetric and non-symmetric polynorbornadienes having a variety of ester groups and carboxyl groups were synthesized by ring-opening metathesis polymerization (ROMP) with Grubbs' third generation catalyst (G3 or [Ru]-III catalyst) in a controlled living manner from half-esters prepared by the selective monohydrolysis of symmetric diesters that we previously reported. The half-esters thus obtained can be directly submitted to ROMP with the G3 catalyst, leading to mostly the trans structure and narrow polydispersity indexes. The subsequent hydrogenation yielded saturated polymers, improving the thermostabilities according to the T5 d results. Our selective monohydrolysis reactions combined with ROMP initiated by the G3 catalyst have proven to be an efficient tool for the production of a variety of homopolymers with well-controlled structures in a living manner. |
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言語 |
en |
| 出版者 |
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出版者 |
Royal Society of Chemistry |
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言語 |
en |
| 出版者版へのリンク |
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言語 |
en |
|
表示名 |
10.1039/d2ra07779e |
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URL |
https://doi.org/10.1039/d2ra07779e |
| DOI |
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関連タイプ |
isIdenticalTo |
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識別子タイプ |
DOI |
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関連識別子 |
10.1039/D2RA07779E |
| ISSN |
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収録物識別子タイプ |
EISSN |
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収録物識別子 |
2046-2069 |
| 権利 |
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|
権利情報 |
© 2023 The Author(s). Published by the Royal Society of Chemistry |
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言語 |
en |
| 著者版フラグ |
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出版タイプ |
VoR |
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出版タイプResource |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
d2ra07779e.pdf (682 KB)
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