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Micellar Mechanisms for Desymmetrization Reactions in Aqueous Media
http://hdl.handle.net/10258/0002000064
http://hdl.handle.net/10258/000200006425d66fa3-b797-4336-9ae6-52dddaa70b2c
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
ao3c04318.pdf (2 MB)
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| アイテムタイプ | 学術雑誌論文 / Journal Article.(1) | |||||||||||||||||
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| 公開日 | 2023-10-05 | |||||||||||||||||
| 書誌情報 |
en : ACS Omega 巻 8, 号 37, p. 33819-33824, ページ数 6, 発行日 2023 |
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| タイトル | ||||||||||||||||||
| タイトル | Micellar Mechanisms for Desymmetrization Reactions in Aqueous Media | |||||||||||||||||
| 言語 | en | |||||||||||||||||
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| 言語 | eng | |||||||||||||||||
| 資源タイプ | ||||||||||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
| 資源タイプ | journal article | |||||||||||||||||
| 著者 |
庭山, 聡美
× 庭山, 聡美
× 平賀, 良知
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| 抄録 | ||||||||||||||||||
| 内容記述タイプ | Abstract | |||||||||||||||||
| 内容記述 | Water-mediated organic reactions significantly contribute to the protection of the environment. Desymmetrization reactions, which convert only one of the identical functional groups within one molecule, are cost-effective because of the low cost of the starting materials. In combination with these two merits, highly efficient and practical selective monohydrolysis reactions of symmetric diesters were previously reported. The products of these reactions are versatile building blocks. The mechanisms of this reaction are hypothesized to proceed through micellar aggregates in which the hydrophilic carboxylate anions formed by monohydrolysis are directed outward and the remaining hydrophobic groups are directed inward in governing the selectivities. Here, dynamic light scattering and electrophoretic light scattering experiments were performed for detection of the key intermediates in the reaction. These experiments revealed the existence of aggregates with negative charges on the surface in the mainly aqueous media, supporting the reaction mechanisms that control the high selectivities. | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 出版者 | ||||||||||||||||||
| 出版者 | American Chemical Society | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| DOI | ||||||||||||||||||
| 関連タイプ | isIdenticalTo | |||||||||||||||||
| 識別子タイプ | DOI | |||||||||||||||||
| 関連識別子 | 10.1021/acsomega.3c04318 | |||||||||||||||||
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| 関連タイプ | isIdenticalTo | |||||||||||||||||
| 識別子タイプ | PMID | |||||||||||||||||
| 関連識別子 | 37744792 | |||||||||||||||||
| ISSN | ||||||||||||||||||
| 収録物識別子タイプ | EISSN | |||||||||||||||||
| 収録物識別子 | 2470-1343 | |||||||||||||||||
| 権利 | ||||||||||||||||||
| 権利情報 | © 2023 The Authors. Published by American Chemical Society. | |||||||||||||||||
| 言語 | en | |||||||||||||||||
| 著者版フラグ | ||||||||||||||||||
| 出版タイプ | VoR | |||||||||||||||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||
