{"created":"2024-07-04T01:47:04.811944+00:00","id":2000225,"links":{},"metadata":{"_buckets":{"deposit":"f7a668f7-d317-4aa2-a633-49e2e37673a8"},"_deposit":{"created_by":20,"id":"2000225","owner":"20","owners":[20],"pid":{"revision_id":0,"type":"depid","value":"2000225"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:02000225","sets":["216:1720052604296","46"]},"author_link":[],"control_number":"2000225","item_1716855451295":{"attribute_name":"日付","attribute_value_mlt":[{"subitem_date_issued_datetime":"2025-03-14","subitem_date_issued_type":"Available"}]},"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2024-03-14","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"3","bibliographicPageEnd":"1078","bibliographicPageStart":"1071","bibliographicVolumeNumber":"69","bibliographic_titles":[{"bibliographic_title":"Journal of Chemical & Engineering Data","bibliographic_titleLang":"en"}]}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Phase separation temperatures of alcohol mixtures of imidazolium-based ionic liquid(IL), 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([Cnmim][TFSA]) and 1-alkyl-3-methylimidazolium tetrafluoroborate ([Cnmim][BF4]) have been measured in order to elucidate effects of alkyl-chain lengths and isomers of alcohols on phase behavior of IL+alcohol mixtures. The investigated IL+alcohol mixtures showed a liquid-liquid upper critical solution temperature (UCST) type phase behavior. The phase separation temperatures of IL+alcohol mixtures increased with elongating the alkyl-chain length of alcohol. The phase separation temperatures of IL+butanol mixtures were higher in the order of 2-methyl-1-propanol (i-BuOH) 　 1-butanol (1-BuOH) > 2-butanol (2-BuOH) > 2-methyl-2-propanol (t-BuOH). On the other hand, the isomerism effects of propanols on the phase separation temperatures were hardly observed. The upper critical solution temperatures Tc obtained from the phase separation temperatures decreased linearly with elongating the alkyl-chain length of ILs.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_language":"en","subitem_link_text":"https://doi.org/10.1021/acs.jced.3c00613","subitem_link_url":"https://doi.org/10.1021/acs.jced.3c00613"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society","subitem_publisher_language":"en"}]},"item_79_relation_18":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1021/acs.jced.3c00613","subitem_relation_type_select":"DOI"}}]},"item_79_rights_19":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2024 American Chemical Society","subitem_rights_language":"en"}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-9568","subitem_source_identifier_type":"PISSN"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"embargoed access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_f1cf"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNames":[{},{}]}],"creatorNames":[{"creatorName":"Shimomura Takuya","creatorNameLang":"en"},{"creatorName":"下村　拓也","creatorNameLang":"ja"}],"familyNames":[{},{}],"givenNames":[{},{}]},{"creatorNames":[{"creatorName":"Usui Masahiro","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2025-03-14"}],"displaytype":"detail","filename":"acs.jced.3c00613.pdf","filesize":[{"value":"896 KB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://muroran-it.repo.nii.ac.jp/record/2000225/files/acs.jced.3c00613.pdf"},"version_id":"37b4fa24-9034-4b7e-8c98-46b18eb72431"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Liquid-Liquid Equilibria","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Imidazolium-based Ionic Liquid","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Alcohol","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Isomerism Effects","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Effects of Alkyl Chain Lengths and Isomers of Alcohols on the Phase Behavior of 1-Alkyl-3-methylimidazolium-Based Ionic Liquid + Alcohol Mixtures","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Effects of Alkyl Chain Lengths and Isomers of Alcohols on the Phase Behavior of 1-Alkyl-3-methylimidazolium-Based Ionic Liquid + Alcohol Mixtures","subitem_title_language":"en"}]},"item_type_id":"79","owner":"20","path":["46","1720052604296"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-07-04"},"publish_date":"2024-07-04","publish_status":"0","recid":"2000225","relation_version_is_last":true,"title":["Effects of Alkyl Chain Lengths and Isomers of Alcohols on the Phase Behavior of 1-Alkyl-3-methylimidazolium-Based Ionic Liquid + Alcohol Mixtures"],"weko_creator_id":"20","weko_shared_id":-1},"updated":"2024-07-04T02:28:34.808760+00:00"}