{"created":"2023-06-19T10:27:16.508359+00:00","id":6178,"links":{},"metadata":{"_buckets":{"deposit":"ceaf7f8b-f5c6-4d63-b26c-758a1aa3440a"},"_deposit":{"created_by":18,"id":"6178","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"6178"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00006178","sets":["216:223","216:407:294","46"]},"author_link":["199","198","44649","52105","44652","44650","197","44648"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-07","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"21","bibliographicPageEnd":"2530","bibliographicPageStart":"2521","bibliographicVolumeNumber":"83","bibliographic_titles":[{"bibliographic_title":"Philosophical magazine","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A new thiospinel CuCrZrS4 has been successfully synthesized by a solid-state chemical reaction. This CuCrZrS4 exhibits ferromagnetic properties below the Curie temperature at Tc=60±2 K. The appearance of irreversible effect between field-cooled and zero-field-cooled magnetization is prominent below around 5 K in a magnetic field of less than 150 Oe. The ac susceptibility χAC shows a rapid decrease below about 10 K. This low magnetic-field behaviour indicates the existence of a re-entrant spin-glass phase below about 10 K. The dc magnetic susceptibility above 100 K shows Curie-Weiss behaviour with an effective magnetic moment of 3.61 μB, which is a little less than the spin-only value of 3.87 μB for the Cr3+ ion. The asymptotic Curie temperature &thetas;p is approximately 65 K, which is a little higher than Tc. The valence state is confirmed to be Cu+Cr3+Zr4+S42- on the basis of magnetic properties. The electrical resistivity ρ shows a semiconducting temperature dependence over the temperature range from 4.2 to 280 K with an activation energy of 6.84×10-3 eV in the higher temperature range from 50 to 283 K","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_text":"10.1080/0141861031000109609","subitem_link_url":"https://doi.org/10.1080/0141861031000109609"}]},"item_79_link_5":{"attribute_name":"室蘭工業大学研究者データベースへのリンク","attribute_value_mlt":[{"subitem_link_text":"戎 修二（EBISU Shuji）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000219_ja.html"},{"subitem_link_text":"近澤 進（CHIKAZAWA Susumu）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000196_ja.html"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Taylor & Francis","subitem_publisher_language":"en"}]},"item_79_relation_15":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"120000801954","subitem_relation_type_select":"NAID"}}]},"item_79_relation_18":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1080/0141861031000109609","subitem_relation_type_select":"DOI"}}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"14786435","subitem_source_identifier_type":"PISSN"}]},"item_79_source_id_14":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11816070","subitem_source_identifier_type":"NCID"}]},"item_79_subject_9":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"428.9","subitem_subject_scheme":"NDC"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"IIJIMA, Yuji","creatorNameLang":"en"}],"familyNames":[{}],"givenNames":[{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"KAMEI, Yasushi","creatorNameLang":"en"}],"familyNames":[{}],"givenNames":[{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"KOBAYASHI, Nami","creatorNameLang":"en"}],"familyNames":[{}],"givenNames":[{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"阿波加,  淳司","creatorNameLang":"ja"},{"creatorName":"AWAKA, Junji","creatorNameLang":"en"},{"creatorName":"アワカ, ジュンジ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"IWASA, Taku","creatorNameLang":"en"}],"familyNames":[{}],"givenNames":[{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{}],"affiliationNames":[{},{}]}],"creatorNames":[{"creatorName":"Ebisu, Shuji","creatorNameLang":"en"},{"creatorName":"エビス, シュウジ","creatorNameLang":"ja-Kana"},{"creatorName":"戎, 修二","creatorNameLang":"ja"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"CHIKAZAWA,  Susumu","creatorNameLang":"en"},{"creatorName":"近澤, 進","creatorNameLang":"ja"},{"creatorName":"チカザワ, ススム","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Nagata,  Shoichi","creatorNameLang":"en"},{"creatorName":"永田, 正一","creatorNameLang":"ja"},{"creatorName":"ナガタ, ショウイチ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-15"}],"displaytype":"detail","filename":"pmag83_2521.pdf","filesize":[{"value":"637.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"pmag83_2521.pdf","objectType":"fulltext","url":"https://muroran-it.repo.nii.ac.jp/record/6178/files/pmag83_2521.pdf"},"version_id":"2bcac405-717c-4421-a84c-d4a1b48892e9"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"chromium compounds","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"copper compounds","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Curie temperature","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"electrical conductivity","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"electrical resistivity","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ferromagnetic materials","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"magnetic hysteresis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"magnetic moments","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"magnetic semiconductors","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"magnetic susceptibility","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"magnetisation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"spin glasses","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"zirconium compounds","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"A new ferromagnetic thiospinel CuCrZrS4 with re-entrant spin-glass behaviour","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"A new ferromagnetic thiospinel CuCrZrS4 with re-entrant spin-glass behaviour","subitem_title_language":"en"}]},"item_type_id":"79","owner":"18","path":["46","223","294"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-01-22"},"publish_date":"2008-01-22","publish_status":"0","recid":"6178","relation_version_is_last":true,"title":["A new ferromagnetic thiospinel CuCrZrS4 with re-entrant spin-glass behaviour"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-11-13T07:11:23.413338+00:00"}