{"created":"2023-06-19T10:27:24.200904+00:00","id":6359,"links":{},"metadata":{"_buckets":{"deposit":"88c5e608-72c5-41e6-b28b-d7bebaee6e9f"},"_deposit":{"created_by":18,"id":"6359","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"6359"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00006359","sets":["216:223","216:407:294","46"]},"author_link":["199","44329","198","44328","52105","197"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2005-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"183","bibliographicPageStart":"177","bibliographicVolumeNumber":"66","bibliographic_titles":[{"bibliographic_title":"Journal of physics and chemistry of solids","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Vanadium garnets NaPb2Co2V3O12 and NaPb2Ni2V3O12 have been successfully synthesized. The X-ray diffraction experiments indicate that these compounds have the garnet structure of cubic symmetry of space group Ia3?d(Oh10) with the lattice constant of 12.742 Å (NaPb2Co2V3O12) and 12.666 Å (NaPb2Ni2V3O12), respectively. The magnetic susceptibility of NaPb2Ni2V3O12 shows the Curie Weiss paramagnetic behavior between 4.2 and 350 K. The effective magnetic moment μeff of NaPb2Ni2V3O12 is 3.14 μB due to Ni2+ ion at A-site and the Weiss constant is -3.67 K (antiferromagnetic sign). For NaPb2Co2V3O12, the simple Curie Weiss law cannot be applicable. The ground state is the spin doublet E2(t26e) and the first excited state is spin quartet T4(t25e), according to Tanabe-Sugano energy diagram on the basis of octahedral crystalline symmetry. This excited spin quartet state just a bit higher than ground state influences strongly the complex temperature dependence of magnetic susceptibility for NaPb2Co2V3O12.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_text":"10.1016/j.jpcs.2004.08.046","subitem_link_url":"https://doi.org/10.1016/j.jpcs.2004.08.046"}]},"item_79_link_5":{"attribute_name":"室蘭工業大学研究者データベースへのリンク","attribute_value_mlt":[{"subitem_link_text":"戎 修二（EBISU Shuji）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000219_ja.html"},{"subitem_link_text":"近澤 進（CHIKAZAWA Susumu）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000196_ja.html"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_79_relation_15":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"120000802294","subitem_relation_type_select":"NAID"}}]},"item_79_relation_18":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.jpcs.2004.08.046","subitem_relation_type_select":"DOI"}}]},"item_79_relation_20":{"attribute_name":"参考URL","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"https://www.elsevier.com/locate/issn/00223697","subitem_relation_type_select":"URI"}}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00223697","subitem_source_identifier_type":"PISSN"}]},"item_79_source_id_14":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00704949","subitem_source_identifier_type":"NCID"},{"subitem_source_identifier":"AA11534013","subitem_source_identifier_type":"NCID"}]},"item_79_subject_9":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"428","subitem_subject_scheme":"NDC"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"Nagata,  Shoichi","creatorNameLang":"en"},{"creatorName":"永田, 正一","creatorNameLang":"ja"},{"creatorName":"ナガタ, ショウイチ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"YAMAGISHI, Takumi","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"AWAKA, Kenji","creatorNameLang":"en"}],"familyNames":[{}],"givenNames":[{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"阿波加,  淳司","creatorNameLang":"ja"},{"creatorName":"AWAKA, Junji","creatorNameLang":"en"},{"creatorName":"アワカ, ジュンジ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{}],"affiliationNames":[{},{}]}],"creatorNames":[{"creatorName":"Ebisu, Shuji","creatorNameLang":"en"},{"creatorName":"エビス, シュウジ","creatorNameLang":"ja-Kana"},{"creatorName":"戎, 修二","creatorNameLang":"ja"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"CHIKAZAWA,  Susumu","creatorNameLang":"en"},{"creatorName":"近澤, 進","creatorNameLang":"ja"},{"creatorName":"チカザワ, ススム","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-15"}],"displaytype":"detail","filename":"jpcs66(1)p177.pdf","filesize":[{"value":"637.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"jpcs66(1)p177.pdf","objectType":"fulltext","url":"https://muroran-it.repo.nii.ac.jp/record/6359/files/jpcs66(1)p177.pdf"},"version_id":"efc78ab8-e494-449c-a2a4-78b1926ca635"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"A. Inorganic compounds","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"A. Oxides","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"B. Chemical synthesis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"D. Magnetic properties","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Magnetic susceptibility of vanadium garnets NaPb2Co2V3O12 and NaPb2Ni2V3O12","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Magnetic susceptibility of vanadium garnets NaPb2Co2V3O12 and NaPb2Ni2V3O12","subitem_title_language":"en"}]},"item_type_id":"79","owner":"18","path":["46","223","294"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-10-02"},"publish_date":"2008-10-02","publish_status":"0","recid":"6359","relation_version_is_last":true,"title":["Magnetic susceptibility of vanadium garnets NaPb2Co2V3O12 and NaPb2Ni2V3O12"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-01-30T07:58:01.312706+00:00"}