@article{oai:muroran-it.repo.nii.ac.jp:00006758, author = {青野, 義道 and AONO, Yoshimichi and 松下, 文明 and MATSUSHITA, Fumiaki and 柴田, 純夫 and SHIBATA, Sumio and 濱, 幸雄 and HAMA, Yukio}, issue = {3}, journal = {Journal of advanced concrete technology : materials, stractures and environment}, month = {Oct}, note = {application/pdf, Pore structural changes in hardened cement pastes, subjected to drying and wetting/drying cycles, were studied at micrometer and nanometer levels. Characterization techniques included Nuclear Magnetic Resonance (NMR), nitrogen and water vapor adsorption, mercury intrusion porosimetry (MIP) and under-water weighing. Coarsening of pore structure was observed with MIP and increase in the true density of C-S-H was suggested by the result of under-water weighing. Decrease in specific surface area due to drying was observed with nitrogen adsorption, and water vapor adsorption associated with Excess Surface Work (ESW) analysis suggested a development of cohesive structure in C-S-H. NMR confirmed polymerization of silicate anion chains. The drying-induced coarsening of pore structure is probably attributed to polymerization of silicate anion chains and development of cohesive structure in C-S-H.}, pages = {313--323}, title = {Nano-structural Changes of C-S-H in Hardened Cement Paste during Drying at 50°C}, volume = {5}, year = {2007}, yomi = {アオノ, ヨシミチ and マツシタ, フミアキ and シバタ, スミオ and ハマ, ユキオ} }