{"created":"2023-06-19T10:27:49.893327+00:00","id":6954,"links":{},"metadata":{"_buckets":{"deposit":"7666ebba-d1df-4a71-894c-a969bf0274db"},"_deposit":{"created_by":18,"id":"6954","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"6954"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00006954","sets":["216:300","216:407:301","46"]},"author_link":["754","43280","4707","4708","41167"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009-06","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"6-7","bibliographicPageEnd":"771","bibliographicPageStart":"765","bibliographicVolumeNumber":"52","bibliographic_titles":[{"bibliographic_title":"Topics in Catalysis","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Effect of Pt precursor and pretreatment on hydrodesulfurization (HDS) activity of Pt/Al-PILM catalyst was examined to prepare highly active Pt-supported HDS catalyst. The order of HDS activities of Pt/alumina-pillared clay montmorillonite (Al-PILM) catalysts prepared by various Pt precursors was Pt(C_5H_7O_2)_2 > H_2PtC_｛l6｝ · 6H_2O > [Pt(NH_3)_4](NO_3)_2 > [Pt(NH_3)_4]C_｛l2｝ · H_2O > H_2Pt(OH)_6. This order was in accordance with that of Pt dispersion. Thus, high Pt dispersion is essential factor to prepare highly active Pt/Al-PILM catalyst for HDS reaction. On the other hand, the effect of pretreatment on the HDS activities of Pt/Al-PILM catalysts prepared by various Pt precursors was also evaluated. The UC-TPS Pt/Al-PILM catalyst showed the highest HDS activity among various pretreated Pt/Al-PILM catalysts, in which uncalcined catalyst was sulfided by temperature programmed sulfidation (TPS). We assumed that high HDS activity of UC-TPS Pt/Al-PILM catalyst is caused by partly sulfided Pt particle with high dispersion. It is concluded that the highly active Pt/Al-PILM catalyst for the HDS reaction could be prepared by using Pt(C_5H_7O_2)_2 as a precursor and UC-TPS treatment.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_text":"10.1007/s11244-009-9204-6","subitem_link_url":"https://doi.org/10.1007/s11244-009-9204-6"}]},"item_79_link_5":{"attribute_name":"室蘭工業大学研究者データベースへのリンク","attribute_value_mlt":[{"subitem_link_text":"神田 康晴（KANDA Yasuharu）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000202_ja.html"},{"subitem_link_text":"上道 芳夫（UEMICHI Yoshio）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000169_ja.html"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Springer 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www.springerlink.com","subitem_rights_language":"en"}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"10225528","subitem_source_identifier_type":"PISSN"}]},"item_79_source_id_14":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1103796X","subitem_source_identifier_type":"NCID"},{"subitem_source_identifier":"AA11959227","subitem_source_identifier_type":"NCID"}]},"item_79_subject_9":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"570","subitem_subject_scheme":"NDC"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open 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タカオ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"UEMICHI,  Yoshio","creatorNameLang":"en"},{"creatorName":"上道, 芳夫","creatorNameLang":"ja"},{"creatorName":"ウエミチ, ヨシオ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"杉岡,  正敏","creatorNameLang":"ja"},{"creatorName":"スギオカ, マサトシ","creatorNameLang":"ja-Kana"},{"creatorName":"SUGIOKA, Masatoshi","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-15"}],"displaytype":"detail","filename":"TopCatal52_765_2009.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"TopCatal52_765_2009.pdf","objectType":"fulltext","url":"https://muroran-it.repo.nii.ac.jp/record/6954/files/TopCatal52_765_2009.pdf"},"version_id":"5281c051-60be-4ac1-8507-f53db6f5bf5e"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Hydrodesulfurization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Supported Pt catalyst","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Alumina-pillared clay montmorillonite","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Pt precursor","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Pretreatment effect","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Preparation of highly active alumina-pillared clay montmorillonite- supported platinum catalyst for hydrodesulfurization","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Preparation of highly active alumina-pillared clay montmorillonite- supported platinum catalyst for hydrodesulfurization","subitem_title_language":"en"}]},"item_type_id":"79","owner":"18","path":["46","300","301"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2012-03-06"},"publish_date":"2012-03-06","publish_status":"0","recid":"6954","relation_version_is_last":true,"title":["Preparation of highly active alumina-pillared clay montmorillonite- supported platinum catalyst for hydrodesulfurization"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-11-06T06:42:22.014895+00:00"}