{"created":"2023-06-19T10:27:54.814550+00:00","id":7072,"links":{},"metadata":{"_buckets":{"deposit":"b19fd0b3-bd9a-4b95-ba9b-5c8314530153"},"_deposit":{"created_by":18,"id":"7072","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"7072"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00007072","sets":["216:246","216:308","46"]},"author_link":["43177","43137","43143","59463","43142","58408","38892","43138"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010-09","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"38","bibliographicPageEnd":"7624","bibliographicPageStart":"7618","bibliographicVolumeNumber":"66","bibliographic_titles":[{"bibliographic_title":"Tetrahedron","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The Diels-Alder reaction of 1,2-dihydropyridine derivatives (1-phenoxycarbonyl-1,2-dihydropyridine 1 or 1-methoxycarbonyl-1,2-dihydropyridine 4) with N-acryloyl (1S)-2,10-camphorsultam (1S)-2 (or N-acryloyl (1R)-2,10-camphorsultam (1R)-2) in the presence of Lewisacid such as titanium tetrachloride, zirconium tetrachloride, and hafnium tetrachloride afforded the endo-cycloaddition product, 2-azabicyclo[2.2.2]octane derivatives in good yields with excellent diastereoselectivity. 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