{"created":"2023-06-19T10:27:59.827851+00:00","id":7193,"links":{},"metadata":{"_buckets":{"deposit":"02254c29-6e51-4ed8-b41e-6f5fb60eb2f0"},"_deposit":{"created_by":18,"id":"7193","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"7193"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00007193","sets":["216:300","216:407:301","46"]},"author_link":["4708","4707"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015-03-01","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1","bibliographicPageEnd":"32","bibliographicPageStart":"20","bibliographicVolumeNumber":"58","bibliographic_titles":[{"bibliographic_title":"Journal of the Japan Petroleum Institute","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Metal phosphide has been widely investigated as a hydrotreating catalyst. The preparation and performance of noble metal phosphide catalyst was examined to develop new phosphide hydrotreating catalysts. The supports affect reducibility of phosphate as a P precursor. Since phosphate does not strongly interact with SiO2 and TiO2 supports, Rh2P was easily formed on these supports. Furthermore, formation of Rh2P enhanced the hydrodesulfurization (HDS) activity of supported Rh–P catalyst. The type of noble metal (NM) and P/NM ratio also strongly affect formation of noble metal phosphide and HDS activity. Excess P facilitates formation of noble metal phosphides at lower reduction temperature. In contrast, excess P causes the aggregation of noble metal phosphide and formation of phosphorus rich noble metal phosphide. Rh–1.5P/SiO2 catalyst had high and stable activity for HDS reaction. Furthermore, this catalyst showed significantly higher hydrodenitrogenation (HDN) activity than sulfided NiMoP/Al2O3 catalyst. Therefore, Rh2P has great potential as a new hydrotreating catalyst.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_text":"10.1627/jpi.58.20","subitem_link_url":"https://doi.org/10.1627/jpi.58.20"}]},"item_79_link_5":{"attribute_name":"室蘭工業大学研究者データベースへのリンク","attribute_value_mlt":[{"subitem_link_text":"神田 康晴（KANDA Yasuharu）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000202_ja.html"},{"subitem_link_text":"上道 芳夫（UEMICHI Yoshio）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000169_ja.html"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"公益社団法人石油学会","subitem_publisher_language":"ja"}]},"item_79_relation_15":{"attribute_name":"論文ID（NAID）","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"130004934944","subitem_relation_type_select":"NAID"}}]},"item_79_relation_18":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1627/jpi.58.20","subitem_relation_type_select":"DOI"}}]},"item_79_rights_19":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"著作権は石油学会にあります。","subitem_rights_language":"ja"}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"13468804","subitem_source_identifier_type":"PISSN"}]},"item_79_source_id_14":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11590615","subitem_source_identifier_type":"NCID"},{"subitem_source_identifier":"AA12022753","subitem_source_identifier_type":"NCID"}]},"item_79_subject_9":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"575","subitem_subject_scheme":"NDC"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{"affiliationNameIdentifier":"10103","affiliationNameIdentifierScheme":"kakenhi"}],"affiliationNames":[{"affiliationName":"室蘭工業大学","affiliationNameLang":"ja"},{"affiliationName":"Muroran Institute of Technology","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"KANDA,  Yasuharu","creatorNameLang":"en"},{"creatorName":"カンダ, ヤスハル","creatorNameLang":"ja-Kana"},{"creatorName":"神田, 康晴","creatorNameLang":"ja"}],"familyNames":[{"familyName":"KANDA","familyNameLang":"en"},{"familyName":"カンダ","familyNameLang":"ja-Kana"},{"familyName":"神田","familyNameLang":"ja"}],"givenNames":[{"givenName":" Yasuharu","givenNameLang":"en"},{"givenName":"ヤスハル","givenNameLang":"ja-Kana"},{"givenName":"康晴","givenNameLang":"ja"}],"nameIdentifiers":[{"nameIdentifier":"4707","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000070447085","nameIdentifierScheme":"NRID","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000070447085"}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":"","affiliationNameLang":"ja"}]}],"creatorNames":[{"creatorName":"UEMICHI,  Yoshio","creatorNameLang":"en"},{"creatorName":"上道, 芳夫","creatorNameLang":"ja"},{"creatorName":"ウエミチ, ヨシオ","creatorNameLang":"ja-Kana"}],"familyNames":[{"familyName":"UEMICHI","familyNameLang":"en"},{"familyName":"上道","familyNameLang":"ja"},{"familyName":"ウエミチ","familyNameLang":"ja-Kana"}],"givenNames":[{"givenName":" Yoshio","givenNameLang":"en"},{"givenName":"芳夫","givenNameLang":"ja"},{"givenName":"ヨシオ","givenNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"4708","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"1000090168659","nameIdentifierScheme":"NRID","nameIdentifierURI":"https://nrid.nii.ac.jp/ja/nrid/1000090168659"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2016-02-15"}],"displaytype":"detail","filename":"58_20.pdf","filesize":[{"value":"1.9 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"58_20.pdf","objectType":"fulltext","url":"https://muroran-it.repo.nii.ac.jp/record/7193/files/58_20.pdf"},"version_id":"62c61c1c-7d18-408f-b0f3-9e22773ca5d1"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Noble metal phosphide","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydrotreating catalyst","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydrodesulfurization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydrodenitrogenation","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Noble Metal Phosphides as New Hydrotreating Catalysts: Highly Active Rhodium Phosphide Catalyst","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Noble Metal Phosphides as New Hydrotreating Catalysts: Highly Active Rhodium Phosphide Catalyst","subitem_title_language":"en"}]},"item_type_id":"79","owner":"18","path":["46","300","301"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2016-01-04"},"publish_date":"2016-01-04","publish_status":"0","recid":"7193","relation_version_is_last":true,"title":["Noble Metal Phosphides as New Hydrotreating Catalysts: Highly Active Rhodium Phosphide Catalyst"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-11-06T06:42:18.187759+00:00"}