@article{oai:muroran-it.repo.nii.ac.jp:00008439, author = {KANDA, Yasuharu and 神田, 康晴 and JANISZEWSKA, Ewa and PAWLESA, Justyna and KOWALAK, Stanislaw and 杉岡, 正敏 and SUGIOKA, Masatoshi}, journal = {室蘭工業大学紀要, Memoirs of the Muroran Institute of Technology}, month = {Feb}, note = {application/pdf, Metallosilicates with MFI structure containing metal atoms such as Ni, Co, Cu, Zn-Cu and Zn in framework have been synthesized with various metal/silicone (Me/Si) ratios (up to 0.1). The acidities of H-form metallosilicates were evaluated by some acid-catalyzed reactions (decomposition of 2-propanol, cracking of cumene and isomerization of 1-butene). The Zn-Si catalyst showed the highest acidities among various metallosilicates. In the metallosilicates-supported noble metal catalysts, 5%Pt/Zn-Si and 0.1%Pd/Cu-Si catalysts showed the highest activities for hydrodesulfurization of thiophene and hydrodechlorination of chlorobenzene, respectively., 研究報告}, pages = {89--95}, title = {Catalytic properties of metallosilicates}, volume = {58}, year = {2009}, yomi = {カンダ, ヤスハル and スギオカ, マサトシ} }