@article{oai:muroran-it.repo.nii.ac.jp:00008893,
 author = {KANDA,  Yasuharu and 神田, 康晴 and TEMMA, Chisato and 天満, 千智 and 澤田, 紋佳 and SAWADA, Ayaka and 杉岡,  正敏 and SUGIOKA, Masatoshi and UEMICHI,  Yoshio and 上道, 芳夫},
 journal = {Applied Catalysis A: General},
 month = {Apr},
 note = {application/pdf, Effects of reduction temperature and phosphorus loading on rhodium phosphide (Rh2P) formation and on the catalytic activity of Rh-xP catalysts for hydrodesulfurization (HDS) were investigated to prepare highly active HDS catalysts. Analysis of the Rh-xP catalysts showed that a suitable P loading for HDS activity is 1.5 wt%—four times greater than that of an Rh catalyst. Temperature-programmed reduction and X-ray diffraction analyses of the Rh-xP catalysts showed that Rh2P is readily formed in catalysts with higher P loading. In contrast, the results of transmission electron microscopy observation and CO adsorption experiments indicated that the Rh2P particle size increased with increasing P content. Thus, the high HDS activity of the Rh-1.5P catalyst was explained by the formation of small Rh2P at a relatively low reduction temperature (550 °C)},
 pages = {410--419},
 title = {Formation of active sites and hydrodesulfurization activity of rhodium phosphide catalyst: Effect of reduction temperature and phosphorus loading},
 volume = {475},
 year = {2014},
 yomi = {カンダ, ヤスハル and テンマ, チサト and サワダ, アヤカ and スギオカ, マサトシ and ウエミチ, ヨシオ}
}