{"created":"2023-06-19T10:29:10.822245+00:00","id":8893,"links":{},"metadata":{"_buckets":{"deposit":"ea409b6d-9fac-4b58-83ed-34ae298c7046"},"_deposit":{"created_by":18,"id":"8893","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"8893"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00008893","sets":["216:300","216:378","216:407:301","46"]},"author_link":["4707","42683","754","42156","4708"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2014-04-05","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"419","bibliographicPageStart":"410","bibliographicVolumeNumber":"475","bibliographic_titles":[{"bibliographic_title":"Applied Catalysis A: General","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Effects of reduction temperature and phosphorus loading on rhodium phosphide (Rh2P) formation and on the catalytic activity of Rh-xP catalysts for hydrodesulfurization (HDS) were investigated to prepare highly active HDS catalysts. Analysis of the Rh-xP catalysts showed that a suitable P loading for HDS activity is 1.5 wt%—four times greater than that of an Rh catalyst. Temperature-programmed reduction and X-ray diffraction analyses of the Rh-xP catalysts showed that Rh2P is readily formed in catalysts with higher P loading. In contrast, the results of transmission electron microscopy observation and CO adsorption experiments indicated that the Rh2P particle size increased with increasing P content. Thus, the high HDS activity of the Rh-1.5P catalyst was explained by the formation of small Rh2P at a relatively low reduction temperature (550 °C)","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_text":"10.1016/j.apcata.2014.01.049","subitem_link_url":"https://doi.org/10.1016/j.apcata.2014.01.049"}]},"item_79_link_5":{"attribute_name":"室蘭工業大学研究者データベースへのリンク","attribute_value_mlt":[{"subitem_link_text":"神田 康晴（KANDA Yasuharu）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000202_ja.html"},{"subitem_link_text":"澤田 紋佳（SAWADA Ayaka）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000166_ja.html"},{"subitem_link_text":"上道 芳夫（UEMICHI Yoshio）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000169_ja.html"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_79_relation_18":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.apcata.2014.01.049","subitem_relation_type_select":"DOI"}}]},"item_79_rights_19":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2014. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0926-860X","subitem_source_identifier_type":"PISSN"},{"subitem_source_identifier":"1873-3875","subitem_source_identifier_type":"EISSN"}]},"item_79_source_id_14":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA1152363X","subitem_source_identifier_type":"NCID"}]},"item_79_subject_9":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open 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loading","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Reduction temperature","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Active site formation","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Formation of active sites and hydrodesulfurization activity of rhodium phosphide catalyst: Effect of reduction temperature and phosphorus loading","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Formation of active sites and hydrodesulfurization activity of rhodium phosphide catalyst: Effect of reduction temperature and phosphorus 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