{"created":"2023-06-19T10:29:24.872840+00:00","id":9259,"links":{},"metadata":{"_buckets":{"deposit":"47a50119-30f7-4990-89f2-b13f788c8d55"},"_deposit":{"created_by":18,"id":"9259","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"9259"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00009259","sets":["216:300","216:378","216:407:301","46"]},"author_link":["754","42156","4707","4708"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-04-10","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"31","bibliographicPageStart":"25","bibliographicVolumeNumber":"515","bibliographic_titles":[{"bibliographic_title":"Applied Catalysis A: General","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"In this study, the low-temperature synthesis of rhodium phosphide (Rh2P) on alumina (Al2O3) using triphenylphosphine (TPP) as a phosphorus (P) source and its catalytic activity toward hydrodesulfurization (HDS) were investigated to prepare a highly active HDS catalyst. TPP was more easily reduced than phosphate, and Rh2P was formed in the P(T)/Rh/Al2O3 catalyst prepared from TTP at lower temperature as compared with the temperature required by Rh-P(A)/Al2O3 catalyst prepared from a phosphate precursor. However, after reduction at a low temperature (450 °C), excess P covered the surface of Rh2P. The optimal reduction temperature for HDS rate of the P(T)/Rh/Al2O3 catalyst (650 °C) was lower than that of the Rh-P(A)/Al2O3 catalyst (800 °C). Furthermore, this temperature was slightly higher than the optimal reduction temperature for CO uptake (600 °C). These results are explained as follows: HDS rate is increased by both elimination of excess P on the active sites at higher reduction temperatures and enhancement of the crystallinity of Rh2P. Furthermore, because the particle size of the P(T)/Rh/Al2O3 catalyst (ca. 1.2 nm) was substantially smaller than that of the Rh-P(A)/Al2O3 catalyst, the P(T)/Rh/Al2O3 catalyst exhibited greater HDS rate compared with the Rh-P(A)/Al2O3 catalyst.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_text":"10.1016","subitem_link_url":"https://doi.org/10.1016/j.apcata.2016.01.040"}]},"item_79_link_5":{"attribute_name":"室蘭工業大学研究者データベースへのリンク","attribute_value_mlt":[{"subitem_link_text":"神田 康晴（KANDA Yasuharu）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000202_ja.html"},{"subitem_link_text":"澤田 紋佳（SAWADA Ayaka）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000166_ja.html"},{"subitem_link_text":"上道 芳夫（UEMICHI Yoshio）","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000169_ja.html"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Elsevier","subitem_publisher_language":"en"}]},"item_79_relation_18":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1016/j.apcata.2016.01.040","subitem_relation_type_select":"DOI"}}]},"item_79_rights_19":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"© 2016. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/","subitem_rights_language":"en"}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0926860X","subitem_source_identifier_type":"PISSN"}]},"item_79_source_id_14":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA10821202","subitem_source_identifier_type":"NCID"},{"subitem_source_identifier":"AA1152363X","subitem_source_identifier_type":"NCID"}]},"item_79_subject_9":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNameIdentifiers":[{}],"affiliationNames":[{},{}]}],"creatorNames":[{"creatorName":"KANDA,  Yasuharu","creatorNameLang":"en"},{"creatorName":"カンダ, ヤスハル","creatorNameLang":"ja-Kana"},{"creatorName":"神田, 康晴","creatorNameLang":"ja"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{}],"affiliationNames":[{},{}]}],"creatorNames":[{"creatorName":"澤田, 紋佳","creatorNameLang":"ja"},{"creatorName":"SAWADA, Ayaka","creatorNameLang":"en"},{"creatorName":"サワダ, アヤカ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"杉岡,  正敏","creatorNameLang":"ja"},{"creatorName":"スギオカ, マサトシ","creatorNameLang":"ja-Kana"},{"creatorName":"SUGIOKA, Masatoshi","creatorNameLang":"en"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"UEMICHI,  Yoshio","creatorNameLang":"en"},{"creatorName":"上道, 芳夫","creatorNameLang":"ja"},{"creatorName":"ウエミチ, ヨシオ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-04-11"}],"displaytype":"detail","filename":"A_C_A_515_25-31 .pdf","filesize":[{"value":"1.9 MB"}],"format":"application/pdf","licensetype":"license_5","mimetype":"application/pdf","url":{"label":"A_C_A_515_25-31","objectType":"fulltext","url":"https://muroran-it.repo.nii.ac.jp/record/9259/files/A_C_A_515_25-31 .pdf"},"version_id":"a4fcd964-4ff9-4c63-a8c7-c7053bbb39a0"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Rhodium phosphide catalyst","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Alumina support","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydrodesulfurization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Triphenylphosphine","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Low-temperature synthesis","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Low-temperature synthesis of rhodium phosphide on alumina and investigation of its catalytic activity toward the hydrodesulfurization of thiophene","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Low-temperature synthesis of rhodium phosphide on alumina and investigation of its catalytic activity toward the hydrodesulfurization of thiophene","subitem_title_language":"en"}]},"item_type_id":"79","owner":"18","path":["46","378","300","301"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-07-24"},"publish_date":"2017-07-24","publish_status":"0","recid":"9259","relation_version_is_last":true,"title":["Low-temperature synthesis of rhodium phosphide on alumina and investigation of its catalytic activity toward the hydrodesulfurization of thiophene"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-11-06T06:42:21.473918+00:00"}