@article{oai:muroran-it.repo.nii.ac.jp:00009722, author = {川村, 幸裕 and KAWAMURA, Yukihiro and DEMINAMI, Shingo and 出南, 真吾 and SALAMAKHA, Leonid and SIDORENKO, Andrey and HEINRICH, Patrick and MICHOR, Herwig and BAUER, Ernst and 関根, ちひろ and SEKINE, Chihiro}, issue = {2}, journal = {Physical Review B}, month = {Jul}, note = {application/pdf, In this paper, we report the transport, thermodynamic, and superconducting properties of a new filled skutterudite CaOs4P12 synthesized under high pressure and high temperature. The electrical resistivity of 3.4–4.8 mΩcm, carrier concentration of 3.8–6.1 × 1020cm−3, and positive Hall coefficient suggest that CaOs4P12 is a semimetal with hole carriers. An anomaly due to low-energy optical modes corresponding to an Einstein temperature of 150 K was observed in the specific heat. Resistivity, dc magnetic susceptibility, and specific heat measurements indicate bulk superconductivity below 2.5 K. The specific heat anomaly at Tc, ∆C/γTc ≈ 1.4, is in agreement with the BardeenCooper-Schrieffer (BCS) value of 1.43. The electron-phonon coupling constant λep is estimated to be 0.47. CaOs4P12 is classified as a BCS-type, weakly coupled type-II superconductor with an upper critical field of Hc2 ≈ 22 kOe and Ginzburg-Landau coherence length of ξ ≈ 12 nm.}, title = {Filled skutterudite superconductor CaOs4P12 prepared by high-pressure synthesis}, volume = {98}, year = {2018}, yomi = {カワムラ, ユキヒロ and デミナミ, シンゴ and セキネ, チヒロ} }