{"created":"2023-06-19T10:29:52.487739+00:00","id":9936,"links":{},"metadata":{"_buckets":{"deposit":"05512a6b-707c-46e3-9206-461bf7fad097"},"_deposit":{"created_by":18,"id":"9936","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"9936"},"status":"published"},"_oai":{"id":"oai:muroran-it.repo.nii.ac.jp:00009936","sets":["216:315","46"]},"author_link":["56018","56020","56019","4704","56021","56017"],"item_79_biblio_info_10":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2019-03-12","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"24","bibliographicPageEnd":"6169","bibliographicPageStart":"6162","bibliographicVolumeNumber":"25","bibliographic_titles":[{"bibliographic_title":"Chemistry A European Journal","bibliographic_titleLang":"en"}]}]},"item_79_description_23":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_79_description_7":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The mechanoresponsive behaviour and photochemical response of a new bis(cyanostyryl)benzene fluorophore (CSB-5) were investigated. Green fluorescence with λem,max of 507 nm was found for CSB-5 in chloroform solution, mirroring the behaviour of a previously reported similar dye (CSB-6).On the other hand, crystalline samples of CSB-5 exhibited orange fluorescence with λem,max of 620 nm, attributable to excimer emission.Although the emission color change was not clearly noticeable by naked eye, CSB-5 exhibited mechanochromic luminescence, due to transformation into the amorphous state upon grinding the crystalline powder.Interestingly, rubbed films of CSB-5 prepared on glass substrates exhibited a pronounced emission color change from orange to green when exposed to UV light.This response is the result of a photochemical reaction that occurs in the amorphous state and which causes a decrease of the excimer emission sites so that the emission color changes from excimer to monomer.The crystalline material did not display such a photoinduced emission color change and the difference in photochemical reactivity between crystalline and amorphous states was exploited to pattern the emission color of rubbed films.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_79_link_17":{"attribute_name":"出版者版へのリンク","attribute_value_mlt":[{"subitem_link_text":"10.1002/chem.201900120","subitem_link_url":"https://doi.org/10.1002/chem.201900120"}]},"item_79_link_5":{"attribute_name":"室蘭工業大学研究者データベースへのリンク","attribute_value_mlt":[{"subitem_link_text":"中野 英之(NAKANO Hideyuki)","subitem_link_url":"http://rdsoran.muroran-it.ac.jp/html/100000238_ja.html"}]},"item_79_publisher_11":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Wiley Online Library","subitem_publisher_language":"en"}]},"item_79_relation_18":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"10.1002/chem.201900120","subitem_relation_type_select":"DOI"}}]},"item_79_rights_19":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This is the peer reviewed version of the following article:Mechano- and Photoresponsive Behavior of aBis(cyanostyryl)benzene Fluorophore, which has been published in final form at https://doi.org/10.1002/chem.201900120. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.","subitem_rights_language":"en"}]},"item_79_source_id_12":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0947-6539","subitem_source_identifier_type":"PISSN"}]},"item_79_source_id_14":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA11617391","subitem_source_identifier_type":"NCID"}]},"item_79_subject_9":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431","subitem_subject_scheme":"NDC"}]},"item_79_version_type_21":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open 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ヨシミツ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"KATAO, Shohei","creatorNameLang":"en"},{"creatorName":"片尾, 昇平","creatorNameLang":"ja"},{"creatorName":"カタオ, ショウヘイ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[],"affiliationNames":[{"affiliationName":""}]}],"creatorNames":[{"creatorName":"TAMAOKI, Nobuyuki","creatorNameLang":"en"},{"creatorName":"玉置, 信之","creatorNameLang":"ja"},{"creatorName":"タマオキ, ノブユキ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"WEDER, Christoph","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorAffiliations":[{"affiliationNameIdentifiers":[{}],"affiliationNames":[{},{}]}],"creatorNames":[{"creatorName":"Nakano,  Hideyuki","creatorNameLang":"en"},{"creatorName":"中野, 英之","creatorNameLang":"ja"},{"creatorName":"ナカノ, ヒデユキ","creatorNameLang":"ja-Kana"}],"familyNames":[{},{},{}],"givenNames":[{},{},{}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2020-03-12"}],"displaytype":"detail","filename":"CEJ_25_24_6162_6169.pdf","filesize":[{"value":"1.4 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"CEJ_25_24_6162_6169","objectType":"fulltext","url":"https://muroran-it.repo.nii.ac.jp/record/9936/files/CEJ_25_24_6162_6169.pdf"},"version_id":"c0b36a06-3ecc-4faf-bd5d-a0a4cd2929ca"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"fluorescence","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"emission color change","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"morphology","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"photochemical reaction","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"bis(cyanostyryl)benzene analogue","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Mechano- and Photoresponsive Behavior of a Bis(cyanostyryl)benzene Fluorophore","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Mechano- and Photoresponsive Behavior of a Bis(cyanostyryl)benzene Fluorophore","subitem_title_language":"en"}]},"item_type_id":"79","owner":"18","path":["46","315"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2019-05-23"},"publish_date":"2019-05-23","publish_status":"0","recid":"9936","relation_version_is_last":true,"title":["Mechano- and Photoresponsive Behavior of a Bis(cyanostyryl)benzene Fluorophore"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-02-14T00:06:10.732376+00:00"}