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Electrochemical Behavior of Polyaniline-zeolite Composite Electrodes I. Redox of Copper-zeolites
http://hdl.handle.net/10258/604
http://hdl.handle.net/10258/60458227616-b077-4d89-a3e2-af0de5513a31
名前 / ファイル | ライセンス | アクション |
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kiyo44_rikou_pp57-65.pdf (751.3 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2014-03-04 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Electrochemical Behavior of Polyaniline-zeolite Composite Electrodes I. Redox of Copper-zeolites | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
WANG, Baochen
× WANG, Baochen× YUAN, Jinghui× 冨士川, 計吉 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A composite electrode has been prepared by press of a mixture of zeolite and Teflonized acetylene black on platinum net and mooified with a conducting polymer,polyaniline by means of electrochemical polymerization. The electrodes have been investigated for electrochemical reactions of cupric ion as a function of type of zeolite Y or A, method of ion-exchange,and solution acidity. Oxidation potential of the trapped ion at zeolite shifted considerably in the anodic direction and the shift was interpreted as the cluster size of zero valent copper (Cu⁰) resulted in an energy shift of its redox reactions. Thus copper ion participating the redox reactions should exist within the pore sites of zeolite. The electrochemical response depended strongly on solution acidity. Polyaniline interfered for copper ion to concentrate in zeolite. The mechanisms of copper ion exchange and the polyaniline modification effect were discussed on the basis of acid-baseproperty of these substances. | |||||
言語 | en | |||||
書誌情報 |
ja : 室蘭工業大学研究報告. 理工編 en : Memoirs of the Muroran Institute of Technology. Science and engineering 巻 44, p. 57-65, 発行日 1994-11-25 |
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出版者 | ||||||
言語 | ja | |||||
出版者 | 室蘭工業大学 | |||||
論文ID(NAID) | ||||||
関連タイプ | isIdenticalTo | |||||
識別子タイプ | NAID | |||||
関連識別子 | 110000351875 | |||||
日本十進分類法 | ||||||
主題Scheme | NDC | |||||
主題 | 541.62 | |||||
ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 05802415 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00238225 | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf |