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An efficient synthesis of chiral isoquinuclidines by Diels-Alder reaction using Lewis acid catalyst
http://hdl.handle.net/10258/659
http://hdl.handle.net/10258/6597671ee0f-07db-4e0d-95b1-518750e515fd
名前 / ファイル | ライセンス | アクション |
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Tetrahedron_66(38)p7618-7624.pdf (775.2 kB)
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Item type | 学術雑誌論文 / Journal Article.(1) | |||||||||||||||||
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公開日 | 2011-09-08 | |||||||||||||||||
タイトル | ||||||||||||||||||
言語 | en | |||||||||||||||||
タイトル | An efficient synthesis of chiral isoquinuclidines by Diels-Alder reaction using Lewis acid catalyst | |||||||||||||||||
言語 | ||||||||||||||||||
言語 | eng | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | Alkaloid | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | 1,2-Dihydropyridine | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | Isoquinuclidine | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | Diels-Alder reaction | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | Lewis acid catalyst | |||||||||||||||||
キーワード | ||||||||||||||||||
言語 | en | |||||||||||||||||
主題Scheme | Other | |||||||||||||||||
主題 | Diastereoselectivity | |||||||||||||||||
資源タイプ | ||||||||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||
資源タイプ | journal article | |||||||||||||||||
アクセス権 | ||||||||||||||||||
アクセス権 | open access | |||||||||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||||||
著者 |
HIRAMA, Masafumi
× HIRAMA, Masafumi× KATO, Yuji× 関, 千草
WEKO
43177
× 中野, 博人
WEKO
59463
× 竹下, 光弘× OSHIKIRI, Noriko× IYODA, Masahiko× 松山, 春男 |
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室蘭工業大学研究者データベースへのリンク | ||||||||||||||||||
関 千草(SEKI Chigusa) | ||||||||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000264_ja.html | ||||||||||||||||||
室蘭工業大学研究者データベースへのリンク | ||||||||||||||||||
中野 博人(NAKANO Hiroto) | ||||||||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000161_ja.html | ||||||||||||||||||
抄録 | ||||||||||||||||||
内容記述タイプ | Abstract | |||||||||||||||||
内容記述 | The Diels-Alder reaction of 1,2-dihydropyridine derivatives (1-phenoxycarbonyl-1,2-dihydropyridine 1 or 1-methoxycarbonyl-1,2-dihydropyridine 4) with N-acryloyl (1S)-2,10-camphorsultam (1S)-2 (or N-acryloyl (1R)-2,10-camphorsultam (1R)-2) in the presence of Lewisacid such as titanium tetrachloride, zirconium tetrachloride, and hafnium tetrachloride afforded the endo-cycloaddition product, 2-azabicyclo[2.2.2]octane derivatives in good yields with excellent diastereoselectivity. The absolute stereochemistry assignment of the endo-cycloaddition product (1S)-5a starting from N-acryloyl (1S)-2,10-camphorsultam (1S)-2hasbeen established to be (1S, 4R, 7S) and the reaction mechanism was proposed. | |||||||||||||||||
言語 | en | |||||||||||||||||
書誌情報 |
en : Tetrahedron 巻 66, 号 38, p. 7618-7624, 発行日 2010-09 |
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出版者 | ||||||||||||||||||
言語 | en | |||||||||||||||||
出版者 | Elsevier Ltd. | |||||||||||||||||
出版者版へのリンク | ||||||||||||||||||
10.1016/j.tet.2010.07.026 | ||||||||||||||||||
https://doi.org/10.1016/j.tet.2010.07.026 | ||||||||||||||||||
DOI | ||||||||||||||||||
関連タイプ | isVersionOf | |||||||||||||||||
識別子タイプ | DOI | |||||||||||||||||
関連識別子 | 10.1016/j.tet.2010.07.026 | |||||||||||||||||
論文ID(NAID) | ||||||||||||||||||
関連タイプ | isVersionOf | |||||||||||||||||
識別子タイプ | NAID | |||||||||||||||||
関連識別子 | 120003339540 | |||||||||||||||||
日本十進分類法 | ||||||||||||||||||
主題Scheme | NDC | |||||||||||||||||
主題 | 434 | |||||||||||||||||
ISSN | ||||||||||||||||||
収録物識別子タイプ | PISSN | |||||||||||||||||
収録物識別子 | 00404020 | |||||||||||||||||
書誌レコードID | ||||||||||||||||||
収録物識別子タイプ | NCID | |||||||||||||||||
収録物識別子 | AA00861787 | |||||||||||||||||
書誌レコードID | ||||||||||||||||||
収録物識別子タイプ | NCID | |||||||||||||||||
収録物識別子 | AA11539786 | |||||||||||||||||
参考URL | ||||||||||||||||||
識別子タイプ | URI | |||||||||||||||||
関連識別子 | https://www.sciencedirect.com/science/journal/00404020 | |||||||||||||||||
著者版フラグ | ||||||||||||||||||
出版タイプ | AM | |||||||||||||||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||||||||||||||
フォーマット | ||||||||||||||||||
内容記述タイプ | Other | |||||||||||||||||
内容記述 | application/pdf |