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New Hybrid-type Squaramide-Fused Amino Alcohol Organocatalyst for Enantioselective Domino Michael Addition/Cyclization Reaction of Oxoindolines with Cyclic 1,3-Diketones
http://hdl.handle.net/10258/00010362
http://hdl.handle.net/10258/00010362f224f9a1-1fa6-488f-944d-f6d4f7e94b0e
名前 / ファイル | ライセンス | アクション |
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AO_3_9_11718_11726 (1.2 MB)
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Item type | 学術雑誌論文 / Journal Article.(1) | |||||||||||||||||||||||
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公開日 | 2021-03-09 | |||||||||||||||||||||||
タイトル | ||||||||||||||||||||||||
言語 | en | |||||||||||||||||||||||
タイトル | New Hybrid-type Squaramide-Fused Amino Alcohol Organocatalyst for Enantioselective Domino Michael Addition/Cyclization Reaction of Oxoindolines with Cyclic 1,3-Diketones | |||||||||||||||||||||||
言語 | ||||||||||||||||||||||||
言語 | eng | |||||||||||||||||||||||
資源タイプ | ||||||||||||||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||||||||||
資源タイプ | journal article | |||||||||||||||||||||||
アクセス権 | ||||||||||||||||||||||||
アクセス権 | open access | |||||||||||||||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||||||||||||
著者 |
チェンアプラム, マデュー
× チェンアプラム, マデュー× オウォラビ, イシアカ アラデ× 関, 千草
WEKO
43177
× 奥山, 祐子× 權, 垠相× 上井, 幸司
WEKO
911
× 常盤, 峻士× 竹下, 光弘× 中野, 博人
WEKO
59463
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室蘭工業大学研究者データベースへのリンク | ||||||||||||||||||||||||
関 千草(SEKI Chigusa) | ||||||||||||||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000264_ja.html | ||||||||||||||||||||||||
室蘭工業大学研究者データベースへのリンク | ||||||||||||||||||||||||
上井 幸司(UWAI Koji) | ||||||||||||||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000240_ja.html | ||||||||||||||||||||||||
室蘭工業大学研究者データベースへのリンク | ||||||||||||||||||||||||
中野 博人(NAKANO Hiroto) | ||||||||||||||||||||||||
http://rdsoran.muroran-it.ac.jp/html/100000161_ja.html | ||||||||||||||||||||||||
抄録 | ||||||||||||||||||||||||
内容記述タイプ | Abstract | |||||||||||||||||||||||
内容記述 | The new hybrid-type squaramide-fused amino alcohol containing both a Bronsted basic site and hydrogen bondingsites in the molecule showed a high catalytic activity as an l organocatalyst in the enantioselective domino Michael addition/cyclization reaction of oxoindohnes with cyclic 1,3-etones to afford'the chiralsproonjugate oxindoles featuring 2-aminopyrans fusing with l carbo-heterocyclic ring systems with l excellent chemical yields (up Ito 98%) and enantioselectivities (up to 95% ee). The obtained chiral spiroconjugated 2-aminopyrans bearing quaternary stereogenic carbon center could be used as l synthetic precursors for several natural products that ave a broad spectrum Iof fascinating biological activities. | |||||||||||||||||||||||
言語 | en | |||||||||||||||||||||||
書誌情報 |
en : ACS OMEGA 巻 3, 号 9, p. 11718-11726, 発行日 2018 |
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言語 | en | |||||||||||||||||||||||
出版者 | AMER CHEMICAL SOC | |||||||||||||||||||||||
出版者版へのリンク | ||||||||||||||||||||||||
10.1021/acsomega.8b01271 | ||||||||||||||||||||||||
https://doi.org/10.1021/acsomega.8b01271 | ||||||||||||||||||||||||
DOI | ||||||||||||||||||||||||
関連タイプ | isIdenticalTo | |||||||||||||||||||||||
識別子タイプ | DOI | |||||||||||||||||||||||
関連識別子 | 10.1021/acsomega.8b01271 | |||||||||||||||||||||||
日本十進分類法 | ||||||||||||||||||||||||
主題Scheme | NDC | |||||||||||||||||||||||
主題 | 499 | |||||||||||||||||||||||
ISSN | ||||||||||||||||||||||||
収録物識別子タイプ | EISSN | |||||||||||||||||||||||
収録物識別子 | 2470-1343 | |||||||||||||||||||||||
権利 | ||||||||||||||||||||||||
言語 | en | |||||||||||||||||||||||
権利情報 | https://creativecommons.org/licenses/by/4.0/ | |||||||||||||||||||||||
著者版フラグ | ||||||||||||||||||||||||
出版タイプ | VoR | |||||||||||||||||||||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||||||||||||||
フォーマット | ||||||||||||||||||||||||
内容記述タイプ | Other | |||||||||||||||||||||||
内容記述 | application/pdf |